This image was taken by more girlfriend, Kaitlynn Little.  I started by making a selection of the original photo around the eye, and moving it to its own layer.  After that, I used adjestment layers to remove all color from the original photo.  I then used the hue and saturation adjusment to pull out the red, and only the red of the eye.  I then used the vibrant adjustment to make the color more vibrant.  The other color was a happy accident.  At the time I had not realized that there was some blue and black around the eye.

Original photo:

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